Search results for "chemistry [Water]"
showing 10 items of 2369 documents
Os, Sr, Nd, Pb, O isotope and trace element data from the Ferrar flood basalts, antarctica: evidence for an enriched subcontinental lithospheric sour…
1996
Os, Sr, Nd, Pb and O isotopes and trace element data are reported for basaltic andesite and andesite whole rocks and, in part, for selected mineral separates from the Jurassic Ferrar flood basalt province. Radiogenic Sr (> 0.709), unradiogenic Nd (εNd= −3 to −5), and radiogenic Pb isotopes, as well as low Nb/La ratios of 0.4 – 0.6 and Nb/La ratios between 0.45 and 0.6 are found for all rocks including our most primitive sample (Mg# = 71.9). This indicates involvement of either continental crust or enriched lithospheric mantle in magma genesis. 187Re/188Os correlates strongly with 187Os/188Os, with an age of 172 ± 5 Ma, in agreement with published Arsingle bondAr data. Initial 187Os/188Os of…
Source Mechanisms of Laboratory Earthquakes During Fault Nucleation and Formation
2021
Identifying deformation and pre-failure mechanisms preceding faulting is key for fault mechanics and for interpreting precursors to fault rupture. This study presents the results of a new and robust derivation of first motion polarity focal mechanism solutions (FMS) applied to acoustic emission (AE). FMS are solved using a least squares minimization of the fit between projected polarity measurements and the deviatoric stress field induced by dilatational (T-type), shearing (S-type), and compressional (C-type) sources. 4 × 10 cm cylindrical samples of Alzo Granite (AG, porosity <1%) and Darley Dale Sandstone (DDS, porosity ≈14%) underwent conventional triaxial tests in order to investigat…
On the formation of laminated sediments on the continental margin off Pakistan: the effects of sediment provenance and sediment redistribution
2001
Abstract The sedimentary processes and sediment sources contributing to the formation of laminated sediments along the upper slope off Pakistan are unravelled using inorganic bulk sediment geochemistry of 43 surface cores from the Pakistani continental margin and additional geochemical and Pb and Nd-isotope data for different types of layers. An important process everywhere along the margin is redeposition of fluvial-derived detritus from the shelf onto the slope. This process is of considerably higher intensity along the Makran margin than on the Indus margin. Trace element enrichment related to early diagenesis or surface productivity, which is commonly detectable in bulk sediment composi…
On the growth of maars and diatremes and its relevance to the formation of tuff rings
1986
Small and large maars exist associated with small and large diatremes, respectively, their subsurface feeder structures. The problem of size and growth of maar-diatreme volcanoes is discussed from a phreatomagmatic point of view from field data, some geophysical data, and short-lived historic maar eruptions. A hydrostatic pressure barrier of usually about 20–30 bars is assumed to control the maximum depth level of explosive magma/groundwater interactions. Similar to the situation in submarine and subglacial volcanism, initial maar-forming water vapour explosions are therefore assumed to occur at shallow depth and to produce a small maar with a shallow diatreme. Because of limited availabili…
Volcanic Gas Emissions Along the Colombian Arc Segment of the Northern Volcanic Zone (CAS-NVZ): Implications for volcano monitoring and volatile budg…
2019
Studying spatial and temporal trends in volcanic gas compositions and fluxes is crucial both to volcano monitoring and to constrain the origin and recycling efficiency of volatiles at active convergent margins. New volcanic gas compositions and volatile fluxes are here reported for Nevado del Ruiz, Galeras, and Purace, three of the most persistently degassing volcanoes located in the Colombian Arc Segment of the Northern Volcanic Zone. At Nevado del Ruiz, from 2014 to 2017, plume emissions showed an average molar CO2/S-T ratio of 3.9 +/- 1.6 (S-T is total sulfur, S). Contemporary, fumarolic chemistry at Galeras progressively shifted toward low-temperature, S-depleted fumarolic gas discharge…
Tracking dynamics of magma migration in open-conduit systems
2016
Open-conduit volcanic systems are typically characterized by unsealed volcanic conduits feeding permanent or quasi-permanent volcanic activity. This persistent activity limits our ability to read changes in the monitored parameters, making the assessment of possible eruptive crises more difficult. We show how an integrated approach to monitoring can solve this problem, opening a new way to data interpretation. The increasing rate of explosive transients, tremor amplitude, thermal emissions of ejected tephra, and rise of the very-long-period (VLP) seismic source towards the surface are interpreted as indicating an upward migration of the magma column in response to an increased magma input r…
Dendropoma lower intertidal reef formations and their palaeoclimatological significance, NW Sicily
1999
Abstract Most carbonate rocky shores of NW Sicily are marked by a coalescence of shells of the gastropod Dendropoma in a construction that is variably developed as a response to wave impact. Here, we review all the available information on these constructions and find that the fossil reefs are reliable sea-level indicators. The thickness of the reef samples never exceeds 30–40 cm below sea-level, whereas all 14 C dates fall within a range of few centuries. Some small fragments ejected by violent sea storms date back to 2500 years cal BP. No samples older than 6200 years cal BP have been detected so far. The present distribution of Mediterranean vermetid platforms should result from a northw…
Geochemical investigations of submarine volcanic exhalations to the east of Panarea, Aeolian Islands, Italy
1991
Abstract Results are presented on scubadiving investigations carried out on thermal manifestations in the area of Panarea (Aeolian Islands). The area investigated falls inside a caldera which extends from the main island to the group of islets located to the northeast. The distribution of the gaseous manifestations is regulated by the NE-SW, NW-SE and N-S regional tectonic directrices, through which the more recent basic magma intruded, giving rise to dikes and pillow lavas. f O 2 -temperature relation of the gases sampled in the investigated area was calculated to be: log f O 2 = 11−24,593/ T which indicates that a buffering mechanism acted on the gases as they cooled down during their asc…
Geochemical modeling of mixing between magmatic and hydrothermal gases: the case of Vulcano Island, Italy
1999
Abstract In this study we present a geochemical approach to model the mixing of magmatic and hydrothermal gases. Our model is based on a rigorous formulation of a perfectly dimensioned system of mass and energy balance equations. Inputs of the equation set are the H2O and CO2 content and gas emission temperature at the surface, together with some constraints gained from the chemical–physical features of the hydrothermal system. The output data give the composition of magmatic gas, mixing fractions and temperatures of gas mixtures in the mixing zone. The comparison of the emission temperature of fumarolic gases with their calculated mixing temperatures provides valuable indications on the ex…
Geochemistry and volatile content of magmas feeding explosive eruptions at Telica volcano (Nicaragua)
2017
Telica volcano, in north-west Nicaragua, is a young stratovolcano of intermediate magma composition producing frequent Vulcanian to phreatic explosive eruptions. The Telica stratigraphic record also includes examples of (pre)historic sub-Plinian activity. To refine our knowledge of this very active volcano, weanalyzedmajor element composition and volatile content of melt inclusions fromsomestratigraphically significant Telica tephra deposits. These include: (1) the Scoria Telica Superior (STS) deposit (2000 to 200 years Before Present; Volcanic Explosive Index, VEI, of 2–3) and (2) pyroclasts from the post-1970s eruptive cycle (1982; 2011). Based on measurements with nanoscale secondary ion…